Monday, 1 October 2018

Carbon Capture Potentials, Problems and Progress


Carbon Capture and Storage involves the capture of the CO2 produced from fossil fuel combustion via chemical absorption and then release, with the gas being compressed and pumped along pipes for storage in empty undersea oil and natural gas wells or other geological strata.  It is sometimes claimed that CCS can reduce emissions from the use of fossil fuel by 80-89%, although in practice its overall efficiency may be more like 60-70%, since the various CCS processes use energy and supplying that adds more emissions. Coal CCS is usually harder and more expensive than fossil gas CCS, partly because, to get high efficiency, the coal has to be gasified as a first stage.

Permanent storage is obviously the ideal, but some doubt whether it can be achieved reliably over very long periods, depending on the location and its geology.  Oil and natural gas were trapped underground in strata safely for eons, so it is argued that replacing them with compressed CO2 should not involve extra risks. However, accidental rupture and rapid release of large volumes of gas could be very dangerous, although some of the gas may, in time, combine with rocks to form new solid calcium carbonate deposits. Some experience with geological injection and storage has been gained from Enhanced Oil Recovery using injected gas, although very long term storage would involve new challenges.

CCS has been seen a vital, with the IEA arguing that, globally, ‘CCS could deliver 13% of the cumulative emissions reductions needed by 2050 to limit the global increase in temperature to 2°C (IEA 2DS). There was also some urgency, with  Oxford Prof. Myles Allen arguing that ‘early investment in carbon dioxide disposal is crucial because most of the cheapest options, like underground storage, will take decades to develop and gain public acceptance’.

Biomass with Carbon Capture (BECCS) too has attracted interest, since it would be carbon negative. The ETI has estimates that BECCS could supply around 10% of UK power along with substantial net carbon reduction, servicing around 10GW of power generation and other industrial sources fitted with CCS. However, views differ on the need for and viability of BECCS. Clearly its progress depends on the success of CCS, as well as the development bioenergy technology and the necessary sustainable sources- its wide scale use implies a significant increase in biomass production.

Progress on CCS has been slow, with concerns about the cost leading the UK to abandon its £1 billion CCS competition. That was seen by some as very unwise. However the slow down was replicated elsewhere, with work on the flagship US Kemper coal CCS project being halted.  Norway, already a CCS pioneer with its enhanced oil recovery technology, has now cut its CCS funding. Some project work continues, and there are some working projects like the Petra Nova project in the USA. But the overall message seems to be that for the moment it is ‘game over’ for CCS in the EU especially. The UK Department of Business, Energy and Industrial Strategy projections in late 2017 had CCS at only 1GW installed in the UK by 2035, and that may be optimistic:

These setbacks will not be welcomed by those who see CCS as the best way to secure a future for fossil fuel, or by those who believe CCS and/or BECCS are vital to reduce carbon emissions.  Most recent energy scenarios have included CCS as a key element, and some have included BECCS, although the emphasis has varied. For example, while the IEA sees CCS as important for the power and industrial sectors, and also backs BECCS, IRENA see CCS as being deployed exclusively in the industry sector, with conventional renewables dominating.

Certainly CCS can be used for carbon emissions from industrial processes as well as from power plants. It may be that, given the slow down in CCS development, this will be the main focus, since, some argue, it offers an easier way to decarbonise industrial activities, than replacing fossil fuel with renewables. That is debatable: it depends of the industrial process,  although, if, rather than CCS, carbon capture and utilization is adopted (i.e. CCU) then some industries may find it possible to develop new products and synfuels. In general, CCU does look more attractive than CCS given that it offers the potential for new valuable products and it may be that, unlike CCS, it will prosper in some sectors. Though that is not clear- renewables may offer a better overall decarbonisation outcome.  That also seems to be the case for the idea of air capture of CO2- a very long shot, given that the proportion of CO2 in ait is much less than that in power plant exhausts.

The prospects for BECCS, or indeed BECCU, are even less clear. Those concerned about the environmental impact of the use of biomass are inevitably unhappy with BECCS. They see it as having major land use impacts and as undermining important carbon sinks. In a report for Chatham House, Duncan Brack says The reliance on BECCS of so many of the climate mitigation scenarios reviewed by the IPCC is of major concern, potentially distracting attention from other mitigation options & encouraging decision makers to lock themselves into high-carbon options in the short term on the assumption that the emissions thus generated can be compensated for in the long term.

Progress on the various carbon capture option discussed above is clearly limited, with some  greens welcoming that: they see carbon capture as deflecting support from renewables. Some also similarly see the current focus on fossil-derived hydrogen as in the H21 project proposed  for Leeds, as a diversion from a switch to genuinely ‘green hydrogen’ produced using renewables sources (with no need for CCS). Others however see this developments as a possible step on the way to the adoption of renewable hydrogen, and as way to establish greener gas in the heating market, ready for later replacement by fully green bio gas and P2G syngas gas, when that becomes available on a wide scale.

It is important to defend renewables against diversions, but it is still the case that fossil fuels remain the dominant suppliers, and they will be so for some while.  In which case, if carbon emission reduction is seen as urgent, then clean-up options are also urgent, if only perhaps as interim measures, while development of renewables proceeds - all in the context of a diminishing reliance on fail fuels. But then we have to decide which options to back! It’s  easier just to say no to them all! However, the issues have to be faced, and in a context where renewables are dominant and a diminishing reliance on fossil fuel has been agreed, that may be less threatening. 

A new book The Long Goodbye on exiting from coal, out next year, explores these issue further. It’s also interesting to see that the Global Warming Policy Foundation has published a report by Prof. Gordon Hughes which argued that CCS, coal CCS especially, is expensive and ineffective. Indeed it says ‘for China, investment in the transmission grid to permit wind generation in the west to be managed jointly with hydro plants in the rest of the country is a far cheaper way of reducing CO2 emissions in the next 10–15 years than retrofitting existing coal plants with CCS or building new coal plants with CCS’. Not what you’d expect from a GWPF report!







Saturday, 1 September 2018

Energy storage - all in flux


Energy storage is all the rage, as costs fall and the use of variable renewables expands. The boom started back in 2016, when grid linked battery storage grew by 50% to 1.7GW globally, according to IRENA. By then there was 1.6 GW of electro-mechanical storage, 3.1GW of heat storage, but all of this dwarfed by the 150GW of pumped hydro. The boom has continued since, for Lithium Ion batteries especially, with Tesla making much of the running, and some see that as continuing, with 55% growth per annum expected up to 2022:
Although the media is also awash with stories other clever, or sometimes odd, new ideas, including mass-based gravity stores http://www.forbes.com/sites/mikescott/2018/02/09/dropping-a-weight-down-a-disused-coal-mine-is-the-new-way-to-store-energy-and-it-might-just-work/ - 2118f5fd1497, liquid air stores http://www.powermag.com/grid-scale-liquid-air-energy-storage-plant-is-launched/ and giant underground caverns storing pressurised air or hydrogen. http://www.greentechmedia.com/articles/read/enlisting-abandoned-oil-and-gas-wells-as-electron-reserves As well as batteries for everything!

However, while the field is full of innovation at present, pumped hydro storage continues to dominate, although that has limits and there are few other major options as yet for large scale grid balancing, especially for longer-term energy storage, as this EASAC report makes clear: http://www.easac.eu/fileadmin/PDF_s/reports_statements/Electricity_Storage/EASAC_Electricity_Storage_Full_Report.pdf

It is also worth noting that storage only one option for grid balancing: ‘There is nothing that storage can do that something else can’t do - flexibility can be provided by a lot of competitors’. http://www.euractiv.com/section/electricity/news/storage-not-fundamentally-needed-for-future-power-grid-scientists-say/  Storage offers one way to respond to the variability of some renewables, but there are other options, including smart grid demand management (to time-shift demand peaks) and supergrid imports and exports (to balance local supply and demand variations across wide areas).

What is needed varies depends crucially on whether the requirement is for short term balancing (for a few seconds, minutes or perhaps a few hours) or longer term storage (for days, or even weeks). Batteries, capacitors, and flywheels, along with smart-grid demand adjustments, may all be fine for brief periods, dealing with short-term variations in renewable inputs, but are not much use for longer-term lulls in renewable availability. Pumped hydro projects may be able to deliver power for perhaps a day or so, depending on their scale, but for longer term storage that’s when big hydrogen gas or compressed air underground storage facilities may come into their own- linked to back-up generators. The stores can be charged using green energy already produced, when there was surplus, locally or on a wider basis, with supergrid links for transfers. That’s some way off, although a system is being developed with a 2.1 GW wind farm in Wyoming sending electricity by a HVDC power grid 525 miles to an underground salt cavern compressed air storage facility in Utah and then, after conversion back to electricity, 490 miles on to Los Angeles.

So there are really two different markets- one for large systems and longer term storage, the other, usually for small scale systems for short term grid balancing. However, there is some overlap. Indeed, confusingly, while domestic scale battery storage, to back-up home PV arrays, is quite popular these days, some say that storage is more efficient, in energy and cost terms, at the utility scale, though there are conflicting views and interpretations: http://www.nature.com/articles/nenergy20171

Certainly though, at whatever sale, batteries are doing well, with falling prices for Lithium Ion batteries being the main driver- making use of technology initially developed for electric vehicles. Bloomberg New Energy Finance says that they expect the lithium-ion battery market for energy storage to be worth at least $239 bn between now and 2040: ‘Utility-scale batteries increasingly compete with natural gas to provide system flexibility at times of peak demand. Small-scale batteries installed by house holds and businesses alongside PV systems will account for 57% of storage worldwide by 2040’. https://about.bnef.com/new-energy-outlook/

However, while Lithium Ion batteries seem to be a winner for now in the battery field, the storage field generally is expanding rapidly, with a dizzying array of new battery technologies and ambitious claims as to their performance potentials. Here are just two battery examples: http://www.renewableenergyworld.com/articles/2017/02/new-hydronium-ion-battery-presents-opportunity-for-sustainable-grid-scale-storage.html and http://news.stanford.edu/2017/02/07/stanford-engineers-create-low-cost-battery-storing-renewable-energy/

Flow batteries are often seen as the big new thing. They involve the use of two separate fluids, but so far these have been toxic and can degrade, so some efforts have been centred on looking for alternatives e.g. organic materials: http://aziz.seas.harvard.edu/electrochemistry and long lasting materials: http://www.seas.harvard.edu/news/2017/02/long-lasting-flow-battery-could-run-for-more-than-decade-with-minimum-upkeep. For a market overview see: http://www.idtechex.com/redox Some Flow Battery ideas are quite dramatic, for example, underground cavern storage of the binary fluids for a huge redox flow battery system: http://www.renewableenergyworld.com/articles/2017/06/german-utility-planning-storage-project-in-salt-caverns.html

So that’s an option for large scale or longer term storage. But, for that, others also look to other electro-chemical conversion routes, such as electrolysis- to produce hydrogen gas, which can be stored (if necessary for long periods) ready for use in a fuel cells or gas turbine to generate power when needed. The Power to Gas (P2G) idea is being followed up in Germany, using surplus electricity from wind projects, with, in some cases, the resultant hydrogen being converted to methane gas, which has multiple uses.  Since P2G is a multi-stage process, the overall energy conversion efficiency can be low, and costs high, but efficiencies are improving and a study has suggested that, longer term, P2G could still win against pumped hydro on environmental sustainability terms: http://link.springer.com/article/10.1007%2Fs10098-016-1250-8

As can be seen, the storage field is still wide open, with many rival routes being promoted at a range of scales: there are many more than looked at above: http://iopscience.iop.org/book/978-0-7503-1531-9. It can be hard to assess all the claims. Some do not stay the course, with some projects collapsing e.g.: http://www.greentechmedia.com/articles/read/Redflow-halts-delivery-of-residential-flow-batteries Some also back out strategically: http://www.greentechmedia.com/articles/read/bosch-abandons-ev-battery-manufacturing Given this fluid situation, there can certainly been problems for those trying to decide which options to back.

Moreover, all this, so far, has been about storing electricity, directly or indirectly. Arguably, heat is a much better storage medium- higher energy density and low cost, with some renewables able able to produce it directly (solar, biomass, geothermal) other indirectly (e.g. wind powered mechanical heat churns, or just by resistance heating). But that’s another story, with a different set of issues, including debates over whether heat should be stored locally near the point of use, or whether it can be sent long distances efficiently. Some say so (20-30 miles), with the trade offs being between temperature, pipe diameter and heat flow rates. Big biogas-fired CHP is then an option, backed up by big heat stores, offering flexible heat and power outputs. That may turn out to be the best energy balancing option in some locations.


However, for the moment, given its low cost, we will probably just continue to use (fossil) gas fired turbines for most grid balancing. Certainly storing gas before combustion is still a much easier option than storing electricity once it has been generated. But hopefully some of these conventional gas plants will be switched over to using biogas or green syngas from P2G, so as to reduce the carbon emissions, with waste heat also being recycled wherever possible. That would be part of the change that is underway in the overall power system. The new post-generation storage options looked at above can also be part of it, including electricity and heat storage options, but the whole thing needs to be reconfigured into an optimal flexible balancing package. See: http://iopscience.iop.org/book/978-0-7503-1230-1